Nanoparticles answer an alchemical mystery | News


The mystery behind why the first reported high explosive, fulminating gold, produces a purple smoke when it detonates has been solved, finally resolving a 400 year-old alchemical puzzle.

Fulminating gold is a mixture of a number of compounds, with gold(III) compounds complexed with ammonia providing most of its explosive punch. Its name comes from the Latin word fulmen, which means lightning.

Fulminating gold was first mentioned by alchemists in the 16th century. When German alchemist Sebald Schwaertzer described its synthesis in 1585, he noted the unusual purple smoke given off when it was detonated. Major scientific figures of the 17th and 18th century – including Robert Hooke, Carl Wilhelm Scheele and Antoine Lavoisier – went on to study it. The material even temporarily blinded Jöns Jakob Berzelius when he dropped a beaker containing a sample in 1809, resulting in glass shards in his eye and permanent, purple-coloured scars on his hand.

However, while the fulminating gold recipe has been understood for centuries, one question has lingered: why does its detonation produce purple smoke?

A smoke trap

Now, Simon Hall’s team at the University of Bristol has confirmed the answer. The most common explanation for the purple smoke is that it contains gold nanoparticles, which look purple because of the way they interact with light. However, the presence of gold nanoparticles in smoke from fulminating gold had never been confirmed experimentally.

The team discovered the smoke from fulminating gold contains spherical gold nanoparticles ranging in size from 30 nm to 300 nm, confirming the theory that the nanoparticles were responsible for the mysterious colour of the smoke. The particles’ presence also explains other mysteries related to fulminating gold, including why Berzelius’ scars were purple, and how it was used by alchemists to coat objects in a purple patina.

‘The work confirms the long-held assumption that the purple fumes of fulminating gold contain elemental gold in the form of nanoparticles,’ says Curt Wentrup, an organic chemist at the University of Queensland, who has researched the topic in the past.

Simon and his team now plan to use the same experimental approach to study the smoke produced by other metal fulminates such as platinum, silver, lead and mercury.

Nina Notman

Reference

J M Uszko et al, arXiv, 2023, DOI: 10.48550/arXiv.2310.15125

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Summary slide with questions and the article for context when teaching 14–16 classes on the nanoparticles: rsc.li/46SoIbe

The team discovered the smoke from fulminating gold contains spherical gold nanoparticles

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